An Innovative Reactive Transport Modeling Approach for the Chemical Evolution of a HLW Cell in the Callovo-Oxfordian Formation
J. Molinero, D. García, M. Grivé, A. Nardi
Amphos 21 Consulting, Barcelona, Spain
Andra (The French National Radioactive Waste Management Agency) envisages the safe disposal of High-Level Waste (HLW) and Intermediate-Level Long-Lived Waste (IL-LLW) in deep geological storage using a multi-barrier system. To ensure the containment of radioactivity, the principle of storage is based on a clay formation with low permeability, homogeneity and continuity (i.e Callovo-Oxfordian ...
Relevance of Hydro-Mechanical-Chemical Processes Involved in the Construction and Operation of Copper Heap Leach Pads
M. Tincopa, A. Nardi, G. Roman-Ross , J. Molinero
Technic University of Catalonia (UPC), Barcelona, Spain
Amphos 21 Consulting, Barcelona, Spain
Heap leaching in the mining industry had become a sophisticated practice at least 500 years ago. It is a mineral processing technology whereby piles of crushed Run-of–Mine rock are leached with chemical solutions to extract minerals. The goal of this work is to contribute to the understanding of the behavior of a heap leach pad by using coupled Hydro-Mechanical-Chemical simulations. COMSOL ...
P. L. Mills, A. Nagaraj
Department of Chemical & Natural Gas Engineering, Texas A&M University, Kingsville, TX, USA
Department of Environmental Engineering, Texas A&M University, Kingsville, TX, USA
Introduction: Development of next-generation chemical processes that have zero emissions is a key environmental objective for sustainable development. The manufacture of H2SO4 by the air oxidation of SO2 to SO3 is an important technology where an opportunity exists for new catalyst development and process innovation by reducing emissions of unconverted SO2 in process reactor tail gases owing to ...
J. Parikh, A. Kapela, N. Tsoukias
Biomedical Engineering Department, Florida International University, Miami, FL, USA
Localized calcium events in the endothelial cells (EC) can modulate smooth muscle cell (SMC) calcium (Ca2+) and membrane potential dynamics through release of endothelium derived hyperpolarizing and relaxing factors. Ca2+ levels in the smooth muscle cell (SMC) determine its contractile state.The underlying complex mechanism regulating the SMC Ca2+ levels and ultimately vessel tone remains poorly ...
Institut für Automatisierungstechnik, Otto-von-Guericke Universität, Magdeburg, Germany
Preparative chromatography is an important separation method where the simulated moving bed (SMB) technology is an increasingly used separation process for binary mixtures. Several chromatographic columns are arranged in a ring where the feedings and drains are changed cyclically to maintain a continuous separation. For this reason, an adaptive controller is proposed to adjust the flow rates ...
IFP, Lyon, Vernaison, France
In a search of concepts for innovative reactors allowing CO2 capture in gas turbine, monolith based chemical looping combustion has been identified as a promising concept. A precise simulation of the chemical looping combustion in a channel of monolith is developed to define the design rules and the material specifications. The objective is also to evaluate this innovative process in terms of ...
S. Pietrzyk, A. Y. Khodakov, and C. Dujardin
Unité Catalyse et Chimie du Solide, Université des Sciences et Technologies de Lille, Ecole Nationale Supérieure de Chimie de Lille, Ecole Centrale de Lille, Villeneuve d’Ascq, France
Operando reactors are used to study, qualitatively and/or quantitatively, active sites of the catalyst and the intermediates of a catalytic heterogeneous chemical reaction, while the reaction is being carried out ("in situ, on-line catalysis studies"). In the present work, an operando reactor using transmission infra-red (IR) absorption spectroscopy has been used to study the Fischer-Tropsch ...
Analysis of Heat, Mass Transport, and Momentum Transport Effects in Complex Catalyst Shapes for Gas-Phase Heterogeneous Reactions Using COMSOL Multiphysics
A. Nagaraj, and P. Mills
Department of Electrical Engineering and Computer Science, Texas A&M University, Kingsville, TX, USA
Department of Chemical and Natural Gas Engineering, Texas A&M University, Kingsville, TX, USA
The global demand for sulfuric acid has been forecast to grow at an average of 2.6% per year from 2005 – 2010. The primary objective of this work is to analyze the performance of various heterogeneous catalyst shapes that have been proposed for the oxidation of SO2 to SO3 used in the manufacture of sulfuric acid. COMSOL Multiphysics provides a powerful numerical platform for simulation of ...
G. Petrone, G. Cammarata, S. Caggia, and M. Anastasi
Department of Industrial and Mechanical Engineering, University of Catania, Catania, Italy
Engineering Maintenance - ISAB Energy Services, Priolo Gargallo, Italy
In this study, COMSOL Multiphysics is applied in order to simulate reacting flows for duct burner systems arranged in the post-firing section of a Heat Recovery Steam Generator of a combined cycle power plant. Two- and three-dimensional simulations are carried out in order to investigate on operative conditions mainly responsible of duct burners overheating. The results are obtained for several ...
B. Srinivasan, J. Hickman, M. Shuler
University of Central Florida, Orlando, FL, USA
Cornell University, Ithaca, NY, USA
A micropump delivers fluid between different components of a microfluidic device in a controlled manner. The elimination of micropump can reduce the design complexity, simplify fabrication, shrink the device footprint and decrease the set-up time required for the operation of the microfluidic device. One such pumpless microfluidic device for body-on-a-chip application for drug toxicity studies ...